SATA > 6-pin adapter. Where to plug in?
The sata connector has a theoretical max current of 1.5 A per contact, and there's 3 contacts for each voltage in the sata connector. So again, if the contact is perfect, you have 12v x 3 contacts x 1.5 A = 12 x 4.5w = 54 watts.
The cables going to the sata connector are AWG18 or AWG16 which can carry a lot of current, but the maximum recommended current is 16A for AWG18 and 22A for AWG16. So basically the cable won't be an issue, it can carry over 200 watts without any problems.
Both pci-e 6 pin connector and pci-e 8 pin connector use only 3 pairs of 12v wires to transfer current. The metal contacts are rated for 5-6A of current each, so since you have 3 pairs of wires that carry 12v, both pci-e 6 pin and pci-e 8 pin can safely push 3 pairs x 6a max per pair x 12v = ~220 watts into a video card.
The PCI-e standard limits the pci-e 6 pin to 75w in the sense that for a video card to be able to say it's pci-e compatible, it must not take more than 75w through a pci-e 6pin connector, and not more than 150w from a pci-e 8 pin connector. The extra 2 wires don't carry more power, they're there just to make it possible for the video card to detect the different connector and take more power.
The idea was to have power supplies that used thinner cables for pci-e 6 pin and fewer connectors (so they could be cheaper) and use thicker cables and use those two extra wires for other things, but those "other things" would have made power supplies more expensive so they gave up on the idea and made everything much simpler.
So anyways, you have a SATA to molex adapter.
Like I said, the sata end can take in 4.5A at 12v = ~ 55w. The molex end can handle up to 5A , or about 60w .. So far so good.
The molex to pci-e 6 pin connector will move the 60w it receives from the 12v wire in the molex connector to the three pairs of wires... you'll still have only 60 watts.
If you use a pci-e 6 pin to pci-e 8 pin, you'll still have only 60w to give to video card but you'll just tell the video card that it's ok to try and take more than 75w.
Basically you shouldn't use sata to anything to power a card with a 8 pin connector unless you know for sure the video card will take less than around 60w trough the 8 pin pci-e connector. It should be fine with pci-e 6pin connectors but nothing else.
There are 2 x molex to PCI-e 6pin/8pin... you have 2 molex connectors, each with max 5a per connector, so you have 12v x 2 connectors x 5A = 120 watts and that's more than pci-e 6 pin and almost as much as pci-e 8pin. Few video cards will constantly take current from pci-e 8pin as close to 150w so you would be fine.
You could use TWO x sata-molex adapters , so that you'd have 2 x 4.5a x 12v = ~ 110 watts. , then connect an adapter that converts 2 molex to pci-e to those 2 molex connectors you just created, and you'll have about 110 watts of safe power to give a video card. For short bursts it may do 150w but it wouldn't be safe.
My advice would actually be to search ebay or some stores for broken / faulty power supplies and CUT the wires with the pci-e 6 pin or 8pin connectors and simply splice the wires to your power supply (on the sata wires or whatever). Worst case, you can cut a sata connector, and connect the wires to 12v and ground of the sata connector - this way you're not limited by the contacts inside the sata connector, your only limitation would be the thickness of the wires going to the sata connector.
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