Whats the difference between MATE, KDE Plasma, LXDE, Cinnamon?
First, choose the right flavor of Linux, not the window-manager / desktop:
As a newbie, you should concern yourself more with the user-friendliness of the distro, programs availability (the ones you need, that is), stability, the community that is there to support you, and of course, suitability for your hardware (in theory you should be buying whatever hardware is required to run your software, not he other way around, but I digress). For example, Mint pioneered including codecs and everything just working out of the box, developed quite a nice software manager/installer that lets you search not only by name, but by task or category, (but it no longer conforms to their long-time-ago philosophy of fitting onto 1 CD). This is why it has steadily moved ahead over the years and is now #1 on the Distrowatch.com list (which is a great place to search for a distro).
If you're looking to revive old hardware, look at PepperMint and Bodhi. Slitaz (80MB) and Porteus (300MB) require impressively little RAM, but aren't as out-of-the-box no-brainers as the former two. If you have more horsepower, take a serious look at Mint. It's an Ubuntu done better, with the absurdities of Canonical's decisions subtracted. Double-bonus. This is really a no-brainer of a choice. You can try Arch derivatives like Manjaro, but you have to be OK with them discontinuing support for 32bit processors. If you have a new and an older computer in the house, there is definitely an advantage of running the same OS on both: easier learning curve.
Once you've decided on your OS (flavor of Linux), only then choose it's color (the window manager, or if you prefer, the desktop environment (wm+apps).
xfce: It used to be that XFCE was the compact more efficient window manager. XFCE was more plain, offered a few compromises but was lightweight. But that was a very long time ago, before other WMs were developed or matured (for example OpenBox, then fancier FluxBox). When you look at the actual size of window managers, you will notice that MATÉ takes up only about half (47% less) megabytes than XFCE. Why would you use xfce if it is no longer more lightweight and there were better choices that used less system resources?
With Maté being the more familiar Gnome2 continuation, which has proven itself from a user-interface standpoint, I don't even consider XFCE anymore, ever. I just don't bother with it, and that would be my recommendation.
Cinnammon (and KDE) should only be used on the latest-crazy-awesomest hardware. Cinnammon is supposed to be an improved Gnome3 environment. If you don't mind it not yet being mature: it is reputed to not be quite as stable, according to reputation, although that should be ironed out over this year. And it has more configuration (adding to system resources being taken up) that you, are not yet ready to explore, and may not for quite some time. Leave it to more experienced users.
KDE was the original Linux desktop environment. So it is normal that old-timers will stick with this. The first programs came out under KDE, people learned to use those, and most hate having to learn new software to do the same old tasks. But it's a memory hog. Today there are plenty of apps for most other environments. And unless you can name a single app that has a name that starts with a K, that you cannot live without and of which there is no equivalent under Gnome (Maté, Cinammon) or LXDE, then don't even bother with it. It's configuration options are for those who don't actually use computers - they just like to tinker with an OS without actually doing any useful work on their puters. (I'm just kidding of course - just a friendly playful jab at the config-freaks).
LXDE is pretty good, but it only shaves a few MegaBytes off of Maté - is it worth it? You won't even notice a few MB - usability will trump a few MB any day. But you'll have to decide which you prefer.
PepperMint6 (forget 7) uses a customized version of LXDE with some xfce components, but you can't configure it much, while Mint is available in Maté (and a few other window-managers / desktop environments).
Slitaz uses JWM (but only needs 30MB of RAM - talk about impressive programming - just add Midori as your efficient web-browser, just don't expect to use FB on Midori - youtube and everything else work fine though, and there's nothing wrong with having 2 browsers for different tasks). Bodhi 4.1 is really a gem - it uses an improved Enlightenment E17 with centralized configuration, and a very user-friendly webinstall where you just visit their website and point at the apps you want to add. Check their apps list before selecting, to make sure they have what you want.
If you are really looking into saving system resources, look into what flavors of Linux use Fluxbox (or Openbox). Those are quite compact. Pretty good programming there. JWM is even smaller, but it's really not fancy (and there is plenty worse out there).
But it may be, that your choice of a WM may not be offered in the Linux distro that is best for you. That could be because of the developers' personal preferences, because of compatibility issues, because of stability issues that may bother some but not others, or other reasons (like diverting development resources to maintaining a version no one wants). Sometimes you just have to trust that the expert developers had their reasons.
Closing word:
Don't blow your window manager's importance out of proportion. It affects the usability of your computer. But, just as with Windoze, it's not going to make your word-processor, your spreadsheet, or your inkscape work any different, no matter what you run them in. And it's your programs you care about. The rest is just window-dressing, and convenience for maintenance.
CAUTION:
In Linux, it is possible to install a program designed for, say KDE, into, say, a Gnome environment. BUT, that will pull in a whole bunch of KDE support programs (called dependencies) that are required behind the scenes to make it work. This will make your system heavier, more resource hungry. So choose wisely. Choose one that suits you, the programs you wish to run, and your system.
Generally speaking, both KDE and Gnome have the largest software app libraries. And Gnome resurrected as Maté (and Cinammon) is lighter. So go with one of those, based on my commentary on them above. Unless you have an old netbook or something - then look at Peppermint6 (not 7, it's much heavier), or Bodhi 4.1 which both are great out of the box, beginner friendly, and run in less RAM.
Below: Window Managers size comparison. This is the latest available, but from a couple of years ago. Things have changed (but not by enough for it to really count).
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