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In case that you want to apply Windows 10 Enterprise Edition (For Enterprise and SA Customers), you will need to visit the VLSC and download the ISO file from there then apply the steps from 12 to 20.

https://blogs.technet.microsoft.com/ptsblog/2015/08/19/how-to-create-a-bootable-usb-stick-or-a-bootable-dvd-for-windows-10/

 

VLSC: https://www.microsoft.com/Licensing/servicecenter/default.aspx

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I believe you just create the USB and then select Enterprise edition during the actual install.

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