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Every time I try to transfer windows to my USB I get this error message "The item “Win10_1909_English_x64.iso” can’t be copied because it is too large for the volume’s format." I am not sure how to fix this problem. I am using my Macbook as well. I have a 32 GB USB. Thanks for everyones help !

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You don't just transfer the .ISO file.

You use the .ISO file to make the USB into a bootable media -- you can use the Media Creation tool directly on Microsoft's site.

 

The downloadable .ISO is for if you want to make the bootable media on your own later

(e.g. on on a USB stick, or DVD, etc).

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