Laptop NAS?
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Solved by Captain_WD,
~snip~
Hey there Jake
Welcome to the community!
I'd first check if the laptop covers the hardware requirements of the OS that you are going to use. The simplest way to use it as a NAS is to map and/or share your folders and your external drives on the network so they can be accessible from anyone.
Have in mind that changing the OS would most probably require you to format your internal drive in order to be used. FreeNAS uses ZFS files system, for example.
You shouldn't have problems sharing external drives on the network, though.
You can consider a standalone NAs solution. Post back if you want me to offer some options. 
Captain_WD.
