Python Issues
For many years, people were hesitant to move from 2.7 to 3. Maybe that's still the case. But with 3.3 and 3.4, it seems at least some people are ready to switch. Example 1 and example 2.
But it seems like a lot of people still want to stick with 2.7 so there's probably no right or wrong choice. Personally, I think I would use the latest version unless I had some reason not to (like compatibility issues with libraries/software I want to use). When it comes down to it, it's not that hard to start learning one and then switching to the other if the need ever arises.
Here are some more differences. And here are the official list of changes if you feel like digging through them.
Finally, you can also always Google "python 2.7 vs 3.4" (or similar types of searches) and look at the articles and discussions. Just remember to look at things that are recent to make sure they are considering the 3.4 version which was released in March 2014.

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