This sounds like an IP address conflict, most likely your devices are receiving or using the same address that they are getting from the university switch, which is why they work individually but not when connected to the unmanaged switch you purchased. You could also be using a static IP, which can be determined by looking at the IP settings for your network adapter on the PC or PS4. If you want both devices to be connected to the internet at the same time, you would most likely need to purchase a router instead of the switch. Connect the internet (WAN) port of the router to the wall jack, then connect your PC and PS4 to the LAN ports, and configure the router to assign IP addresses via DHCP. If the connection to the PC is using a static IP, that would be set as the default gateway for the router.