The only way Thermo-electrical is going to work is if you use it as a stage in a normal loop. the problem is you are dealing with to many joules per second, the peltier is a huge bottle neck for transferring that kind of heat. for direct cpu cooling you would need a surface area probably the size of a dinner plate if not larger. But if you put a peltier block in the loop as a stage before the CPU block you will get a reduction in temps. this will probably not be supper efficient but im willing to bet that you will get a drop in CPU temp from a standard loop.
You go from the CPU to the radiator, then you go from to the radiator to the pump, from the Pump to a Peltier cooled channel block then back into the CPU Block. So you have the CPU block and radiator doing their normal job, and the peltier block cooling the water below ambient temps before being injected into the CPU block.
Another problem with video is that copper transfers heat well but it doesn't dissipate heat so well, its too dense. So cooling copper is going to have more resistance than heating. Aluminum on the other hand will transfer cold quickly, and water will cool exceeding fast.
For your peltier block you use two peltiers sandwiching an aluminum plate with channels drilled parallel to the peltiers, (lots of small channels a few mm from the cooling plate). You cap the ends with etched acrylic to channel water to the drilled pipes, tap your fittings into the Ends of the acrylic. after that you use regular heat sink and fans clamped onto the hot sides of the peltier.