That part I know is connected successfully, since I always hear a click when I put it in perfectly. When the latch is facing a different way, it either doesn't click or get put in at all.
It says the 12v mainly supplies power to the CPU. If the 12V power connector is not connected,the computer will not start. Seens the opposite to me, though.
The 24pin is necessary, since I think it sends power to all the other parts. The 12v pin is... confusing. It doesn't look like I need it, to be honest, but I've read all across the internet that the CPU doesn't work without that plugged in. That was the reason for this thread being created in the first place.