@Fullmental Thank you for being willing to type it all over again! It had me barking up the wrong tree as I interpreted PROCHOT(processor hot?) as some kind of core, or system agent thermal problem.
I added another fan and adjusted the fan curves, no change. I tried to roll back to a previous bios and the Asus flash utility would not take anything but the current bios so I flashed that for the heck of it. I went ahead and scrapped my previous OC settings as I read that the new bios requires a fair amount less voltage for some people. It looks like this bios isnt the bad one but the previous one I was used to and stable on was buggy at the very least. I can now boot at 5ghz with less than 1.3v, I could never even post at 1.3v previously. Now it looks like stability will be near 1.35v instead of 1.4v.
Here is a photo of my current set up with the additional fan up top and the rear set up as an intake now.