Why do you want any SSDs in a backup system?
Does it need to be iSCSI or can it be a regular SMB share? The iSCSI connection is going to always be slower because of the block storage nature of the interface.
You should check this resource on the FreeNAS forum:
https://www.ixsystems.com/community/threads/some-differences-between-raidz-and-mirrors-and-why-we-use-mirrors-for-block-storage.44068/
Normal SSDs are not fast enough to be used as SLOG and you would only need a maximum of 30 or 40 GB of SLOG anyhow. There are some great articles about that here:
The ZFS ZIL and SLOG Demystified http://www.freenas.org/blog/zfs-zil-and-slog-demystified/
Some insights into SLOG/ZIL with ZFS on FreeNAS https://www.ixsystems.com/community/threads/some-insights-into-slog-zil-with-zfs-on-freenas.13633/
Testing the benefits of SLOG using a RAM disk! https://www.ixsystems.com/community/threads/testing-the-benefits-of-slog-using-a-ram-disk.56561/
SLOG benchmarking and finding the best SLOG https://www.ixsystems.com/community/threads/slog-benchmarking-and-finding-the-best-slog.63521/