Use the manuals. Seriously. The ones you need are for will be for the case, motherboard, power supply, and any additional cooling/airflow hardware you have.
Here are the things you'll need to look for in the manuals:
- Power connectors for the motherboard and GPU
- Front I/O (This includes USB, front panel audio, and case buttons)
- Fans/CPU fan headers
- Fan/case RGB headers
- Storage (you'll need to connect most storage to the motherboard as well as the power supply)
If you're having trouble with the RGB headers and power button headers, you definitely should look at the motherboard manual. Everything is labeled nicely there. Also, there are aRGB and RGB headers. A lot of modern motherboards have both, now, but make sure to plug your fans into the one with the right number of pins.