Sure, just measure it in the PCIe connector (black 3 wires closest to lock is Gnd, Yellow furthest away from the lock is +12V) , the probes should be able to feel the connectors while the connector is connected.
Just push them in aside the cables, tested now and they should stay in place, diagonally GND in one corner and +12V in the oposite.. _:::`` . If you have a current probe put all black or yellow through it!!