Hey, @Brandogg255!
Your storage solution looks solid to me, SSDs definitely are a highly reliable solution. You will also notice quite an improvement in performance and speed. I'd keep backups on the WD Green as well, together with all the other big data I want to store safely on it. If you are willing to pay for the SSD's reliability, I'd go for it.
However, I can still suggest you to take a look at WD Black for gaming as well, or maybe even the WD VelociRaptor.
WD Black is an HDD specifically designed for demanding applications and high-end gaming with 64 MB cache and 7200 RPM:
http://www.wdc.com/en/products/products.aspx?id=20
WD VelociRaptor is a 10 000 RPM drive with 64 MB cache as well designed for ultimate performance:
http://www.wdc.com/en/products/products.aspx?id=20
Both drives come with a 5-year warranty, which is a pretty good thing to have when it comes to storage.
Hope this helped.
SuperSoph_WD